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To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Mashers Unite! Successfully land 100 Link Attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

It's Showtime Defeat the Promoter in the Episodes.

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Everybody Needs a Hobby Customize your avatar.

New World Enter the Online Lobby.

Newbie Pal Tamer Caught 10 kinds of Pals

Beginning of the Legend Caught your first Pal

Turn the Tables Win in a group match by using a race bonus

Shut Down Shut down an entire Tower Network

Gearhead Obtain all rewards granted by race count
7/7

CrossWorlds Traveler Race through every CrossWorld in Grand Prix
15/15

Fully Licensed Rank up the Gadget Plate until 6 slots are unlocked
4/4

Grand Slam Win in all Grand Prix
8/8

New Horizons Unlock the Secret Grand Prix

Rival Buster Defeat a rival 5 times
5/5

Loyal Customer Use Donpa Tickets to buy an item

Tinkerer Rank up the Gadget Plate
1/1

Flawless Racing Achieve a perfect win in any Grand Prix

Grand Prix Champion Win any Grand Prix

Star Seeker Get all Red Star Rings in any course

Vengeance for the Milano! As Star-Lord, land 10 KOs with assists from the Guardians of the Galaxy.

Welcome to MASTER DUEL Register the player name

Might of Fuxi As Iron Fist, land 3 KOs with a single use of Living Chi.

Multiverse Tour As Luna Snow, complete a match on 5 maps with different themes.

Way of the Butterfly As Psylocke, contest the mission area for 60 seconds in a single match.

Demon's Roar As Magik, land 3 KOs within a single tranformation into Darkchild.

Justice for All! As Captain America, land 3 KOs with a single use of Freedom Charge.

Terror of the Ten Realms As Hela, land a 3-player KO streak in Yggsgard: Yggdrasill Path.

Inevitable! Win 100 matches.
100/100

Punishment of the Moon As Moon Knight, hit 4 enemies with a single use of Hand of Khonshu.

Assemble! Team up with a friend for a match.

Vicious Vines As Groot, imprison 4 enemies with a single use of Strangling Prison.

Descending Descendant Meet Susano.

Dog Eat Dog Beat Hayabusa's turnip-digging record.

A Village for a Peach Return Kamiki Village back to normal.

Lupine and Divine Earn a Cherry Tree rank for each item in the Results screen.

Tachigami Learn how to use Power Slash.

Yomigami Learn how to use Rejuvenation.

Smoke Screen As the Punisher, land 3 KOs amidst the smoke of Scourge Grenade in a single game.

Rising Star Reach level 20.

"Ahhh, those tiny claws!" As Squirrel Girl, land 3 KOs with a single use of Unbeatable Squirrel Tsunami.

Snack Attack! As Jeff the Land Shark, swallow 4 enemies with a single use of It's Jeff!