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Combo Aficionado Clear 10 combo challenges in Character Lessons.
10/10

To Hell and Back Clear the Samurai Outriders scenario in Episode mode.

To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Tōkon Assemble! Successfully land Tōkon Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

Mashers Unite! Successfully land 100 Link Attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Super Assemble! Successfully land Super Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Kneel Before Doom! Clear the Knights of Doom scenario in Episode mode.

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Heart of a Champion Clear any course in All-Star Arena.

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Everybody Needs a Hobby Customize your avatar.

Ragnarok Win a game in Arcadia Rumble.

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

It's Showtime Defeat the Promoter in the Episodes.

This is Where the Fun Begins Finish a battle in Versus.

The Prelude to Battle Clear the Startup Battle.

Not So Little Friend Unlock the secondary firing mode on a Jackdaw weapon

Silence, Fool! Kill a guard ringing a bell

Smooth Operator Craft an item

A Poxy Bird Captain your own ship (complete Sequence 2, Memory 6)

Backs To The Wall Kill an enemy with a wall takedown

Yo Ho… Learn a new shanty

Lively Havana Get a tour of Havana (complete Sequence 2, Memory 1)

Caped Defender Perform 100 Successful Counters
100/100

The name's Bond. James Bond Collect all trophies

The world is not enough Collect all postcards
10/10

A collector’s habit Find all collectibles
92/92

Casino Royale Collect all playing cards
36/36

A legacy of spycraft Discover all legacy items
9/9

Recovered assets Collect all mementos
14/14

For your eyes only Unlock all MI6 files
23/23

Positively shocking Make an enemy taser another enemy

Keep moving forward Achieve clearance level 3
3/3

Soft landing Tackle an enemy over a ledge

What if...? Complete an Operation in TacSim

The readiness is all Beat tier 3 of an Escalation in TacSim

A change of pace Complete an Escalation in TacSim

For king and country Defend MI6

The writing is on the wall Catch Isola

Solo Leave MI6 as a rogue agent

You know my name Defeat Damien Webb

Double or die Save Theresa Lorca

Always have an exit plan Use a gadget to escape a confrontation

No time to die Escape by helicopter

Firestarter Push an enemy into a fire extinguisher