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To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Super Assemble! Successfully land Super Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Tōkon Assemble! Successfully land Tōkon Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Crossover Event Successfully land Crossover 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

Ragnarok Win a game in Arcadia Rumble.

Ranking Up Without Fear Finish a Ranked Match.

Let's Take It Easy Finish 10 Casual Matches.
10/10

Best. Activity. Ever. Play an Activity within the Open Lobby.

Roll the Tape! View any replay.

Combo Aficionado Clear 10 combo challenges in Character Lessons.
10/10

This is Where the Fun Begins Finish a battle in Versus.

Your Very Own Stamp of Approval Use a Sticker.

Following in Their Footsteps Follow a player.

Everybody Needs a Hobby Customize your avatar.

New World Enter the Online Lobby.

Welcome to the Danger Room Create a room in Room Match.

Champion Buster Clear the Champion Course in All-Star Arena.

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Mashers Unite! Successfully land 100 Link Attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Heart of a Champion Clear any course in All-Star Arena.

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Deadpool Saves the Tōkon Universe Unlock all secret commands for the Command List using Deadpool.

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

It's Showtime Defeat the Promoter in the Episodes.

The Prelude to Battle Clear the Startup Battle.

Let Go Complete all Epilogue requirements and defeat the King.

Never Enough Collect 20 Halcyon in the Yellow Shore.
20/20

Nightmare Strands Enter and complete all 7 Nightmare Gates at least once.
7/7

The Autumn Leaves Complete Pillar of Autumn.

Shattered Glass Complete every encounter inside the Banyan Tree.
4/4

Eclipse’s Gift Collect 70 Halcyon.
70/70

Countermand Stagger 2 hostiles simultaneously with one Parry.

Reinforced Carapace Collect 20 Integrity Augments.
20/20

Carcosan Conqueror Encounter and defeat 10 Alpha hostiles.
10/10

The Blazing Throne Complete Act 3.

King Defeat the Overlord of the Yellow Shore.

Carcosan Surveyor : Gaze of Corruption Frame the throne of Carcosa using Photo Mode.

Carcosan Surveyor : Lighting the Path Frame the beacon of the giant communication device using Photo Mode.

Radiance Damage 3 hostiles simultaneously using the Illumine.

Into Yellow Complete Act 2.

Priestess Defeat the Overlord of the Cathedral.

Carcosan Surveyor : Ringing a Bell Frame the central tuning fork device using Photo Mode.

Shepherd Defeat the Overlord of Acolyte’s Haven.

Angle Of Attack Defeat a hostile using a ricochet Nova Lance slug.

Carcosan Surveyor : Hollowed Foundations Frame the highest tower interior using Photo Mode.