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Crossover Event Successfully land Crossover 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Mashers Unite! Successfully land 100 Link Attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

Everybody Needs a Hobby Customize your avatar.

Roll the Tape! View any replay.

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

Heart of a Champion Clear any course in All-Star Arena.

Ranking Up Without Fear Finish a Ranked Match.

To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Tōkon Assemble! Successfully land Tōkon Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Let's Take It Easy Finish 10 Casual Matches.
10/10

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Combo Aficionado Clear 10 combo challenges in Character Lessons.
10/10

To Hell and Back Clear the Samurai Outriders scenario in Episode mode.

Super Assemble! Successfully land Super Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

With Great Power Comes Great Responsibility Clear the Amazing Guardians scenario in Episode mode.

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

It's Showtime Defeat the Promoter in the Episodes.

Lost My Head Bled Out In Sudden Death

No time to die Escape by helicopter

All time high Infiltrate Nicholas Webb's penthouse

Agent under fire Escape in the bin lorry

You only live twice Defeat the assassin

Positively shocking Make an enemy taser another enemy

A hard man to kill Survive an assassination attempt

Trigger Mortis Escape the ambush alive

Short fuse Shoot at an enemy while he's throwing a grenade

Nobody lives forever Find 009s body

Win, lose or die Win the auction

Disarming personality Disarm an enemy with a laser

Skyfall Jump out of a plane in Slovakia

He'll live Knock out an enemy by shooting him in the legs

I expect you to die Survive the explosion at the hotel in Slovakia

Firestarter Push an enemy into a fire extinguisher

Shaken not stirred Complete your first assignment at the nightclub

From Malta with love Complete your training as a recruit in Malta

Sleight of hand Disarm an enemy by shooting a weapon from their hand

Icebreaker Survive the helicopter crash

The Right Man for the Job Complete Unknown Signal.

Can't Stop, Won't Stop Print all obtainable weapons, hacking nodes, and abilities during the main story.

Escape Artist Unlock every escape hatch.

Peekaboo Win at hide-and-seek.

Scarlet Guardian Completed Phase 0.

Right Back At You Perform 5 Heroic Strikes

Still Not Your Turn Perform 100 Counter Tags

Art’s Working Overtime Complete Character Mastery Level 20 With 1 Character