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To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

It's Showtime Defeat the Promoter in the Episodes.

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

All Clear Complete 5 Corrupted Castles

This is Where the Fun Begins Finish a battle in Versus.

Everybody Needs a Hobby Customize your avatar.

Heart of a Champion Clear any course in All-Star Arena.

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

The Prelude to Battle Clear the Startup Battle.

Limitless Find a legendary piece of gear of each type

Edward Catway Break 50 potted plants

Help A Brother Out Complete a Templar Hunt sequence

Collective Madness Add one of each ship class to Kenway's fleet

The Hangman Kill 10 enemies by hanging them with the rope dart

Gun-kata Use pistols to kill four enemies in a row within five seconds

Return The Favor Dash ram a ramming Brig

Silence, Fool! Kill a guard ringing a bell

Friend To All Interact with all seven friendly animals

Caught 'Em All Catch at least five enemies within a single smoke bomb

Matador Dodge a total of three charge attacks by a Wild Pig

Perfect Predator Get a perfect harpoon shot on a Great White Shark

Old Ironsides Perform 3 perfect braces

Among Thieves Unlock a smuggler's chest

Governor Restore all buildings in the Great Inagua village

Business And Pleasure Spend 50,000 Reales

Walls That Hold Back The Wind Settle in a new home (complete Sequence 4, Memory 1)

Ed the Diver Swim a total of 1000m underwater, excluding underwater shipwrecks

Hungover Wake up in a haystack

Strike The Colors Board a Lead Convoy ship

Not So Little Friend Unlock the secondary firing mode on a Jackdaw weapon

Giant Slayer Assassinate a powerful guardian in one go

Glutton for Nourishment Consume 20 food items

Articles Of Agreement Ensure the survival of all pirates in a street fight

Dressing Overall Equip new cosmetics in each of the Jackdaw's vanity slots

Owned Complete every activity in a single location

Smooth Operator Craft an item

A Poxy Bird Captain your own ship (complete Sequence 2, Memory 6)

Unsinkable Survive a rogue wave taken from the side

Lively Havana Get a tour of Havana (complete Sequence 2, Memory 1)

Backs To The Wall Kill an enemy with a wall takedown

Yo Ho… Learn a new shanty

Rydell's Rydes Fully upgrade your story garage

Tricky Successfully perform any stunt.

The Climb Complete a Standard Arcade Ladder