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To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Tōkon Assemble! Successfully land Tōkon Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

Goddess of Nightmares Earn all other Trophies

Silk and Spitefulness Fulfill the Prophecy 'Silk and Spitefulness'

Improbable Outcomes Fulfill the Prophecy 'Improbable Outcomes'

Chaos in Hell Clear the 'Great Chaos Below' Trial

Sentimental Value Collect every Keepsake

Voice and Vanity Fulfill the Prophecy 'Voice and Vanity'

Elysian Glory Prevail in the Contest of Champions

Bearing Dark Gifts Fulfill the Prophecy 'Bearing Dark Gifts'

Everybody Needs a Hobby Customize your avatar.

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

It's Showtime Defeat the Promoter in the Episodes.

The Prelude to Battle Clear the Startup Battle.

The Unseen Sentinel Fulfill the Prophecy 'The Unseen Sentinel'

Golden Age Reach the epilogue of the story

Power of Sahasrara Successfully hit a True Energy Point Art, outside of Training Mode

Dressed to Kill Reach the final confrontation in an Arachne outfit

Close Comrades Forge a bond with 10 comrades

Unfamiliar Forms Alter the appearance of each Animal Familiar

Beast Master Fully upgrade all Animal Familiars

Check THIS out! Complete a Character Trial.

If I don't try... I'm never going to get it! Complete all Tutorials for one character

Oblivion Obliterated Defeat Vaatu in Story mode

It'll Quest Ya! Request help from Guru Sokka

Sokka Stylin' Win a match with Sokka

The Tides Command This Ship Win a match with every character

Heads Will Roll Discover the hidden threat in Story Mode

Shame and Humiliation Defeat Crazy Azula in Story mode

A 400-foot Tall Purple Platypus Bear with Pink Horns and Silver Wings Win a match with Azula

A New Challenger Approaches! Unlock Nightmare Korra and Avatar State Aang

Nirvana Win a match with Avatar State Aang

Sweatbender Win a match with Katara

MY HONOR!!! Win a match with Zuko

Father of the Year Win a match with Ozai

Flowchart Stance Successfully use Flow Stance against 10 attacks

I didn't ask for all this flying and magic! Check the Command List for a character

I'll Face Myself Win a match with Nightmare Korra

Out of Breath Win a match with Zaheer

No Blind Spots Win a match with Toph

Pressure Point Complete a Critical Hit for any character, outside of Training Mode

Wedger of Worlds Win a match with Kyoshi

Deal With It Win a match with Korra

That's Rough, Buddy Defeat Guru Sokka in Story mode

A Tale of Two Avatars Complete First Chapter in Story Mode