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To Me, My X-Men Clear the Unbreakable X-Men scenario in Episode mode.

Avengers, Assemble! Clear the Fighting Avengers scenario in Episode mode.

It's Showtime Defeat the Promoter in the Episodes.

I Can Do This All Day Finish 500 battles. (Excluding Offline Versus and Training mode.)
500/500

Right Back Atcha! Perform Crossover Reflect 5 times during battle. (Excluding Offline Versus and Training mode.)
5/5

Perfect Timing! Successfully land a Perfect Reflect during battle. (Excluding Offline Versus and Training mode.)

Super Assemble! Successfully land Super Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Mashers Unite! Successfully land 100 Link Attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Deadpool Saves the Tōkon Universe Unlock all secret commands for the Command List using Deadpool.

Tōkon Assemble! Successfully land Tōkon Assemble 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Weapon X Clear 100 combo challenges in Character Lessons.
100/100

Combo Aficionado Clear 10 combo challenges in Character Lessons.
10/10

Champion Buster Clear the Champion Course in All-Star Arena.

The Ultimates Successfully land 10 Ultimate Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Crossover Event Successfully land Crossover 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Super Human Precision Successfully land 10 Super Skills during battle. (Excluding Offline Versus and Training mode.)
10/10

Sidekick! Perform 100 Assemble Assist attacks during battle. (Excluding Offline Versus and Training mode.)
100/100

Saw It Coming a Mile Away Perform 10 Assemble Counters during battle. (Excluding Offline Versus and Training mode.)
10/10

Ranking Up Without Fear Finish a Ranked Match.

Smash! Successfully land Assemble Smash 10 times during battle. (Excluding Offline Versus and Training mode.)
10/10

Let's Take It Easy Finish 10 Casual Matches.
10/10

Welcome to the Danger Room Create a room in Room Match.

Roll the Tape! View any replay.

Wall Breaker Trigger 10 Breaks during battle. (Excluding Offline Versus and Training mode.)
10/10

Following in Their Footsteps Follow a player.

Your Very Own Stamp of Approval Use a Sticker.

Best. Activity. Ever. Play an Activity within the Open Lobby.

This is Where the Fun Begins Finish a battle in Versus.

Heart of a Champion Clear any course in All-Star Arena.

To the Sky! Successfully land 10 Slam Launchers during battle. (Excluding Offline Versus and Training mode.)
10/10

Ragnarok Win a game in Arcadia Rumble.

New World Enter the Online Lobby.

Everybody Needs a Hobby Customize your avatar.

The Prelude to Battle Clear the Startup Battle.

Lacerta's End Defeat Lacerta.

Place of Return Discovered your first shrine.

Rangifer's End Defeat Rangifer.

Entangled Entangle with Koo for the first time.

Knowing Me, Knowing You Have a deep talk with Kagura for the first time.

Man's Best Friend Have a deep talk with Koo for the first time.

Blight-Touched Enhance an attribute for the first time.

First Fire Discovered your first campsite.

Purifier's Mantle Obtain the Purifier's outfit.

Small Town, Big Job You made a big impression at the Paleto Bay Chicken Festival.

A Fair Day's Pay It's time for a little getaway.

Blitzed You performed a classic blitz play.

A Mystery, Solved Solve the mystery of Leonora Johnson.

From Beyond the Stars Collect and return all spaceship parts.

Wanted: Alive or Alive Deliver a bail bond target alive.

Altruist Acolyte Deliver an unsuspecting victim to the Altruist Cult.