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The Cat and the Bat Obtain a key by completing the third Riddler trial.

Master of Fear Wayne vs Crane.

Jekyll & Hyde Stop the bank heist on Miagani Island and lock up the master mind in GCPD.

Double Jeopardy Face off with an old friend.

Gun Pals! Send an item to a friend.

New In Town Complete the mission "Plan B".

Cycle of Violence Use 100 Quick Gadgets while in free flow combat.

Riddler on the Rampage Obtain a key by completing the fourth Riddler trial.

À La Carte Complete 20 Side Missions.
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Pimp My Sidearm Fully mod a weapon.

I Hope You Didn't Tea-bag Win a duel.

Heir To An Empty Castle Complete mission "Cold as the Grave".

The Cult Save the sacrificial victim and lock up the executioner in GCPD.

A Friendship Resurrected With friends like this who needs enemies?

Stay Golden Use a Golden Key.

Cross The Streamers Complete mission "Blood Drive".

The Burning Question Obtain a key by completing the fifth Riddler trial.

Apocalypso! Complete mission "The Great Vault".

The Primal Riddle Obtain a key by completing the sixth Riddler trial.

Stick It To 'Em Kill two or more enemies with a single sticky grenade.

Scar of the Bat Cure the doctor.

Days of Fire Extinguish the fires in Gotham City.

Token Gesture Redeem 25 tokens.

How Do I Look? Unlock 10 customization items.

I Am A Goddess, A Glorious Female Warrior Complete mission "In the Shadow of Starlight".

Damn, Gina Obtain all Vault Rewards.

Bye, Felicia! Complete mission "Divine Retribution".

On Fleek Equip purple-rarity gear or better in every slot.

Savage Metal Smash 10 militia transport vehicles off the road without using the immobilizer.

An Old Flame Complete the mission "Hunting The Firehawk".

Touch of Death Apprehend the weapons dealer and lock him up in GCPD.

Death by Design Obtain a key by completing the seventh Riddler trial.

Mechani-Cool Unlock 10 Vehicle Parts via hijacking.
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The Monster Machine Track down and apprehend the serial killer.

The Road Home Destroy all of the militia APC's.

The Riddle Factory Obtain a key by completing the eighth Riddler trial.

Better Than Money Purchase 5 items from the Black Market.

Bounty Hunter Complete 20 side missions.

No Man Left Behind Complete the mission "A Dam Fine Rescue".

Lethal Pursuits Obtain a key by completing the ninth Riddler trial.

My Name Is Earl Buy 20 cosmetic items from Crazy Earl.
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Angel in the Dark Complete the trials and prove you are a worthy successor.

Nine Lives Obtain a key by completing the last Riddler trial.

Build Buster Kill a Constructor without it ever building another bot.

The Beginning of a Samurai Reached level 10.
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Biggest Badass In The Borderlands Reach level 50.
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Wilhelm Screamed Complete the mission "A Train To Catch".

Sugar Daddy Tip Moxxi $10,000.

Sky's The Limit Complete the mission "Rising Action".

Gates of Gotham Destroy all of the militia watchtowers.