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Bigger Bang Complete story mode on Normal difficulty

Creature of the Night Freedom of the city.

Rope-A-Dope-A-Dope String up one henchman and drop him to surprise a second (any play mode)

Ghost Train Fight for survival

Friends With Benefits Complete the subplot involving Keira Metz.

IQ Test Solve the first riddle

Brotherhood of the Fist Return of the Dynamic Duo.

A Heart Broken in Two Secure the secret base.

Freefall Don't look down

Arkham City Sirens Drop in on an old friend

Conundrum Cracker Solve 55% of Riddler challenges

Night Glider Glide continuously for over 100m

Exit Stage Right All the world is a stage

City of Fear Defend the assault on your ally's fortress.

Death and Glory Perform 20 fear takedowns.

Triple Threat Kill 3 opponents in one fight using 3 different methods (swords, bombs, crossbow, Signs, etc.).

Pieces of the Puzzle Obtain a key by completing the second Riddler trial.

Who Rules The Night Batman vs the Arkham Knight.

Shrieker Complete the contract on the shrieker.

Drive By Stop an armored truck by taking out the driver.

Judgment Day Win the rumble down under.

Fear of Success Survive Scarecrow's ambush.

The Cat and the Bat Obtain a key by completing the third Riddler trial.

Be Not Afraid Win the war for Gotham.

Soldier Complete all chapters on Normal.

Catch! Catch a Batarang (any play mode)

Bombardier Collect the formulae for 6 different bomb types.

Double Jeopardy Face off with an old friend.

Master of Fear Wayne vs Crane.

Stop, Drop, & Roll Defeat 3 Majini at once by setting oil canisters on fire.

Riddler on the Rampage Obtain a key by completing the fourth Riddler trial.

Jekyll & Hyde Stop the bank heist on Miagani Island and lock up the master mind in GCPD.

Stop the Clock Time is running out

A Friend in Need Find and free Dandelion.

Cycle of Violence Use 100 Quick Gadgets while in free flow combat.

The Burning Question Obtain a key by completing the fifth Riddler trial.

Conundrum Rescue the first hostage from Riddler

Mental Athlete Solve 70% of Riddler challenges

The Primal Riddle Obtain a key by completing the sixth Riddler trial.

The Cult Save the sacrificial victim and lock up the executioner in GCPD.

Environmentally Unfriendly Kill 50 opponents using the environment (e.g. swamp gas, insects or objects).

Scar of the Bat Cure the doctor.

Masters of Removing Work together to save someone special.

Broken Toys Destroy it all

Took the Shaman's Path Survived the Shaman's Path and found Ourea's retreat.

Days of Fire Extinguish the fires in Gotham City.

Necromancer Help Yennefer extract information from Skjall's body.

Touch of Death Apprehend the weapons dealer and lock him up in GCPD.

The Doppler Effect Resolve the doppler problem in Novigrad.

Fire in the Hole Destroy 10 monster nests using bombs.