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Flying Ace Pilot the VTOL without getting a scratch on it.

Artificer Make a smithed item, an enchanted item, and a potion

Diplomatic Immunity Complete "Diplomatic Immunity"

Snake Tongue Successfully persuade, bribe, and intimidate

High Voltage Defeat ten enemies with a stun rod charge attack.

You Can Pet the Dog Pet Torgal 5 times.
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Hard Worker Chop wood, mine ore, and cook food

Expert Reach Level 25

Gates of Gotham Destroy all of the militia watchtowers.

Death of Innocents Rescue station 17 fire crew.

Dressed to the Fives Craft or upgrade 5 pieces of gear.
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Taking Care of Business Join the Thieves Guild

Wasteland D.I.Y. Craft 100 Items

Explorer Discover 100 Locations

Extraction Fulton extract an enemy soldier.

Acceptance Accept your fate.

Prepared for the Future Decide the Fate of the Commonwealth

Master Oculist Craft Oculi.

Mankind-Redefined Complete "Mankind-Redefined"

Invisible Predator Complete one predator challenge by using only Silent Takedowns and without being detected

Gotham Underground Defuse all of the militia explosive ordinance in Gotham City.

Biggest Bang Complete story mode on Hard difficulty

Blood Oath Become a member of the Circle

Streets of Gotham Destroy all of the militia checkpoints.

Taking Sides Join the Stormcloaks or the Imperial Army

Prankster's Return Placed A Grenade Or Mine While Pickpocketing

Alduin's Wall Complete "Alduin's Wall"

RobCo's Worst Nightmare Hack 50 Terminals

Tenth Birthday Achieve level 10 with Aurora.

Hard Choice Shoot the helicopter pilot with a Magnum at point-blank range.

Lawless Defy your fate.

Wanted Escape from jail

Horseman Kill 150 demons from horseback
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Armed and Dangerous Create 50 Weapon Mods

Powering Up Complete "Powering Up"

Predator Bronze Achieve 8 medals on predator challenges

Hero of the People Complete 50 Misc Objectives

Dark Allegiances Apprehend Scarecrow's senior commander.

The Nuclear Option Complete "The Nuclear Option"

B.O.W.s Are Ugly Defeat 100 enemies that have come out of a chrysalid.

Improvised Kills Kill 150 enemies with items from the environment
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Elder Knowledge Complete "Elder Knowledge"

Legend Of The Wastes Reach Level 50

Skill Master Get a skill to 100

Nuclear Family Complete "Nuclear Family"

When You Ride Alone Ride Ambrosia for the first time.

…The Harder They Fall Kill 5 Giant Creatures

Freeflow Combo 40 Complete a combo of 40 moves (any play mode)

Blind Betrayal Complete "Blind Betrayal"

They're Not Dolls… Collect 10 Vault-Tec Bobbleheads